该剧原本在FX进行开发，描述了一个发生于17世纪马萨诸塞州的灵异故事。人们认为塞勒姆镇上居住着害人的女巫，但这座小镇背后却隐藏着更加黑暗的、不为人知的超自然秘密。根据该剧的设定，塞勒姆的女巫是真实的——但她们和表面上看起来的模样完全不同，所谓的「塞勒姆审巫案」也与历史传说大相径庭。制片人表示该剧的剧情核心是「惊天地泣鬼神」的爱情，但是也少不了各种超自然、动作和冒险元素。Janet Montgomery扮演塞勒姆最强大的女巫Mary Sibley，美貌，无情，但是又很脆弱。她的丈夫是已经活了很久的、病怏怏的塞勒姆市政委员George Sibley，家中非常富有。Ashley Madekwe扮演Mary的得力助手Tituba，神秘而诡异。她已经和主人分开十年，但她的音容相貌一点都没有改变，她似乎不会变老。Shane West扮演曾经当过10年兵的John Alden，性格刚毅，不苟言笑。他在战场上被印第安人俘虏，被释放后返回家乡塞勒姆。他发现这里已经成了一个捕猎女巫的新「战场」，贵族Cotton Mather是最积极的「女巫猎人」。Seth Gabel扮演当地贵族Cotton Mather，他将猎杀塞勒姆女巫视为己任，并且在猎杀行动中起主导作用。他对塞勒姆居民宣布：「如果任何女人利用自己的美貌来诱惑塞勒姆的好人，犯下纵欲的罪孽，那么她一定是个女巫。」Xander Berkeley扮演塞勒姆市政委员Magistrate Hale，典型的生意人，特别喜欢大排场，喜欢装腔作势。Tamzin Merchant扮演天资聪慧的艺术家Anne Hale，对刚刚到来的John Alden一见钟情，却不知道他和女巫Mary Sibley有一段情史。Anne胆子很大，夜里独自到墓地里去画墓碑，因此见到了Alden。她邀请Alden给自己当模特，此举引发了Mary的怨恨，Mary可能会做出对Anne不利的事情。Elise Eberle扮演Lewis牧师的女儿Mercy，人们相信她已被魔鬼附身。她看起来很强大，实则非常脆弱。
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